Thermal Protective Clothing for Firefighters explores the materials, design, and usage of thermal protective clothing. The characteristics of fire hazards are discussed in detail, and the thermal environments faced by firefighters in these fire hazards are also examined. The different types of potential burn injuries and the heat stress that occurs to firefighters’ bodies when exposed to such thermal environments are analyzed. Furthermore, the development of various high performance fibers and fabrics for thermal protective clothing is discussed. The test methods and existing standards to evaluate the thermal protective and physiological comfort performances of the fabrics and clothing are critically reviewed. Recent developments in the field of fire- and heat-resistant materials have led to significant improvements in thermal protective clothing. In parallel with this, the complexity and risk levels of fires, especially in industrial-storage facilities, and developments in health and safety cultures have increased the demand for high-performance heat- and flame-resistant clothing and equipment, designed to mitigate skin burn injuries and reduce risk of death from fire hazards. Throughout the work, the gaps and limitations in existing test methods and standards are identified, and approaches are recommended for the development of enhanced test methods. Scenario modeling and its implications for firefighters’ protective clothing is discussed, and various factors affecting performance are established. Finally, various key issues related to thermal protective clothing are addressed to guide the future research in the field of thermal protective clothing for firefighters. This book will help materials-textile engineers to develop high performance thermal protective clothing that can enhance the protection, safety, and comfort of firefighters.