Non-Fiction Books:

Light and Matter Id / Licht und Materie Id

Infrared and Raman Spectra of Non-Metals
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Paperback / softback
$300.00
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Description

The dynamical properties of solids have recently attracted renewed interest in connection with the increasing understanding of phase transitions and reĀ­ lated phenomena. In particular, soft modes or, more generally, phonon 'anomĀ­ alies' seem to play an important role in structural and electronic phase tranĀ­ sitions, such as ferroelectric or superconducting transitions. The understanding of the mechanisms responsible for the occurrence of unusually low frequencies in phonon spectra requires a detailed analysis of the microscopic forces governing the lattice vibrations. Of particular importance is the influence of the electronĀ­ lattice interaction in the adiabatic approximation which in many cases is the origin of peculiarities in the phonon self-energy. In this work the vibrational spectra of pure non-metals and of those conĀ­ taining point defects are investigated. ' In these materials the interrelation beĀ­ tween the pseudo-harmonic forces (determining the phonon dispersion reĀ­ lations) and the non-linear anharmonic and electron-phonon forces (as they act in infrared and Raman spectra) is most obvious and can be quantitatively analysed in terms of appropriate models. The main task is to arrive at a physically correct treatment of electronic degrees of freedom, as for example in an electronic 'shell' model, which leads to the description of phonon spectra in terms of long-range polarizabilities and short-range deformabilities. The purĀ­ pose of our review is to stimulate further investigations which, we hope, will result in explicit relations between the parameters of the semi-microscopic models and the matrix elements from the electronic band structure.
Release date NZ
March 10th, 2012
Audience
  • Professional & Vocational
Contributor
  • Edited by L Genzel
Edition
Softcover reprint of the original 1st ed. 1984
Illustrations
XIV, 602 p.
Pages
602
Dimensions
170x244x31
ISBN-13
9783642464355
Product ID
20764123

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