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Investigation of Reactions Involving Pentacoordinate Intermediates on Hardback by Peter A. Byrne
Investigation of Reactions Involving Pentacoordinate Intermediates on Hardback by Peter A. Byrne
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Investigation of Reactions Involving Pentacoordinate Intermediates

The Mechanism of the Wittig Reaction
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Description

In this thesis, the author outlines the discovery of an effect common to representative examples of all Li salt-free Wittig Reactions. The implications of such a universally applicable effect are that all such Wittig reactions occur through the same mechanism. Although the Wittig reaction was first discovered in 1953, its reaction mechanism has never been definitively settled with many different variants proposed and disproved. The work in this thesis shows conclusively that for [2+2] cycloadditions all Wittig reactions occur by the same irreversible mechanism. In addition, the author also describes a new chromatography-free method for the removal of phosphine oxide from the alkene crude product of the Wittig reaction. The work in this thesis has led to several publications in high-profile journals.
Release date NZ
February 7th, 2013
Audience
  • Professional & Vocational
Illustrations
25 Illustrations, color; 8 Illustrations, black and white; XVI, 231 p. 33 illus., 25 illus. in color.
Pages
231
Dimensions
155x235x20
ISBN-13
9783642320446
Product ID
20645794

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Investigation of Reactions Involving Pentacoordinate Intermediates by Peter A. Byrne
$289.00
Investigation of Reactions Involving Pentacoordinate Intermediates
by Peter A. Byrne ~ Paperback / softback
Available - Usually ships in 3-4 weeks

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